Wiki Log
Chronological record of all wiki actions. Append-only. Format:
## [YYYY-MM-DD] action | subject
[2025-05-15] create | Wiki initialized
- Domain: 光电催化与铜基氧化物半导体材料
- Structure created with SCHEMA.md, index.md, log.md
[2025-05-15] ingest | Batch: 4 papers (6 files)
- Paper 1: Cu₂O facet-engineered biomass-polyol conversion (Appl. Catal. B, 2026) — SI only
- Paper 2: CuO morphology for CO₂RR (Adv. Funct. Mater., 2026) — main + SI
- Paper 3: Ternary facet junction Cu₂O PEC urea (ACS Energy Lett., 2026) — main
- Paper 4: Hollow Cu₂O nanoframes DEP (Nat. Commun., 2025) — main + SI
- Raw sources: 5 files in raw/papers/
- Entity pages created: paper1-cu2o-biomass-polyol, paper2-cuo-co2rr-morphology, paper3-cu2o-pec-urea, paper4-cu2o-nanoframes-dep
- Concept pages created: cu2o-facet-engineering, cu2o-morphology-control
[2026-05-17] ingest | Strain-regulated Cu₂O CO₂RR to ethylene
- Source: Advanced Energy Materials paper + supporting information by Yan et al.
- Raw sources captured: raw/papers/paper5-aem-2025-strain-cu2o-co2rr.md, raw/papers/paper5-si-aem-2025-strain-cu2o-co2rr.md
- Entity page created: entities/paper5-strain-cu2o-co2rr-ethylene.md
- Concept pages updated: concepts/cu2o-facet-engineering.md, concepts/cu2o-morphology-control.md
- Index updated: added Paper 5 and refreshed page count/date
[2026-05-17] create | CO₂ electroreduction Cu catalysts concept
- Created concept page: concepts/co2-electroreduction-cu-catalysts.md
- Fixed broken wikilink from entities/paper2-cuo-co2rr-morphology.md
- Index updated: added concept page and refreshed page count
[2026-05-17] ingest | P-doped Cu/Fe₂O₃ electrocatalysts for urea electrosynthesis
- Source: JACS 2025 paper + supporting information by Deng et al.; DOI 10.1021/jacs.5c09805
- Raw sources captured: raw/papers/paper6-phosphorus-doped-cu-fe2o3-urea.md, raw/papers/paper6-si-phosphorus-doped-cu-fe2o3-urea.md
- Entity page created: entities/paper6-p-cu-fe2o3-urea-electrosynthesis.md
- Concept page created: concepts/co2-nitrate-urea-electrosynthesis.md
- Concept/entity pages updated: concepts/co2-electroreduction-cu-catalysts.md, entities/paper3-cu2o-pec-urea.md
- Index updated: added Paper 6 and CO₂/NO₃⁻ urea electrosynthesis concept; refreshed page count
[2026-05-24] ingest | In situ Raman spectroscopic insight of hydrogen spillover in electrocatalytic hydrogenation
- Source: JACS 2026 paper + supporting information by Yan Liu, Ze-Yu Zhang, Jie Wei, Yan Liu, Hua Zhang, Jian-Feng Li; DOI 10.1021/jacs.6c00294
- Raw sources captured: raw/papers/paper7-jacs-2026-hydrogen-spillover-raman.md, raw/papers/paper7-si-jacs-2026-hydrogen-spillover-raman.md
- Entity page created: entities/paper7-hydrogen-spillover-raman.md
- Concept pages updated: concepts/cu2o-facet-engineering.md, concepts/cu2o-morphology-control.md
- Index updated: added Paper 7 and refreshed page count/date
[2026-05-25] ingest | In-situ-grown Cu dendrites plasmonically enhance HER on facet-engineered Cu₂O
- Source: Advanced Materials 2023 paper + supporting information by Zhang et al.; DOI 10.1002/adma.202305742
- Raw sources captured: raw/papers/paper8-advmat-2023-cu-dendrites-plasmonic-her-cu2o.md, raw/papers/paper8-si-advmat-2023-cu-dendrites-plasmonic-her-cu2o.md
- Entity page created: entities/paper8-cu-dendrites-plasmonic-her-cu2o.md
- Concept pages updated: concepts/cu2o-facet-engineering.md, concepts/cu2o-morphology-control.md
- Index updated: added Paper 8 and refreshed page count/date
[2026-05-25] ingest | Ir clusters/Cu₂O N₂ photofixation and cryogenic CO oxidation on Cu₂O
- Source 1: ACS Materials Letters 2024 paper + supporting information by Zhang et al.; DOI 10.1021/acsmaterialslett.4c00577
- Source 2: Angew. Chem. Int. Ed. 2026 paper + supporting information by Karagoz et al.; DOI 10.1002/anie.202515673
- Raw sources captured: raw/papers/paper9-acs-mater-lett-2024-ir-clusters-cu2o-n2-photofixation.md, raw/papers/paper9-si-acs-mater-lett-2024-ir-clusters-cu2o-n2-photofixation.md, raw/papers/paper10-anie-2026-cryogenic-co-oxidation-cu2o.md, raw/papers/paper10-si-anie-2026-cryogenic-co-oxidation-cu2o.md
- Entity pages created: entities/paper9-ir-clusters-cu2o-n2-photofixation.md, entities/paper10-cryogenic-co-oxidation-cu2o.md
- Concept pages updated: concepts/cu2o-facet-engineering.md, concepts/cu2o-morphology-control.md
- Index updated: added Paper 9 and Paper 10; refreshed page count/date
[2026-06-02] ingest | COF-gated Cu₂O nanocubes for nitrate-to-ammonia electrosynthesis
- Source: JACS 2026 paper by Tahir, Wei et al.; DOI 10.1021/jacs.5c16080; journal IF noted from BioxBio as 2024 JIF 15.6 (2025 update)
- Raw source captured: raw/papers/paper11-jacs-2026-cof-cu2o-nitrate-ammonia.md
- Entity page created: entities/paper11-cof-cu2o-nitrate-ammonia.md
- Concept pages updated: concepts/cu2o-facet-engineering.md, concepts/cu2o-morphology-control.md, concepts/co2-nitrate-urea-electrosynthesis.md
- Schema updated: expanded domain and added nitrate-reduction/ammonia-electrosynthesis tags
- Index updated: added Paper 11 and refreshed page count/date
- Note: SI was referenced by main paper but no separate SI PDF was found in local cache during ingest
[2026-06-03] ingest | Cu0-Cu+ dual sites for electrochemical hydrogenation of quinoline
- Source: Advanced Functional Materials 2025 paper by Pan, Bao et al.; DOI 10.1002/adfm.202414120
- Raw source captured: raw/papers/paper12-afm-2025-cu-cu2o-quinoline-hydrogenation.md
- Entity page created: entities/paper12-cu-cu2o-quinoline-hydrogenation.md
- Concept page created: concepts/copper-oxide-organic-electrosynthesis.md
- Concept pages updated: concepts/cu2o-morphology-control.md, concepts/co2-electroreduction-cu-catalysts.md
- Schema updated: added organic-electrosynthesis and electrochemical-hydrogenation tags
- Index updated: added Paper 12 and refreshed page count/date
- Note: SI was referenced by main paper but no separate SI PDF was provided in this chat; exact synthesis recipe details remain to be filled from SI
[2026-06-04] ingest | CPD@CNT modified Cu matrix composites and relevance to Cu electrocatalytic hydrogenation
- Source: Ceramics International 2026 paper by Chen, Cao, Zhao, Liu et al.; DOI 10.1016/j.ceramint.2026.04.440
- Raw source captured: raw/papers/paper13-elsevier-2026-cnt-cu-catalysis.md
- Entity page created: entities/paper13-cpd-cnt-cu-composite-interface.md
- Concept page created: concepts/carbon-nanotubes-in-cu-electrocatalysis.md
- Concept pages updated: concepts/copper-oxide-organic-electrosynthesis.md, concepts/cu2o-morphology-control.md
- Schema updated: expanded domain and added copper-composite/carbon-nanotube/interface-engineering tags
- Index updated: added Paper 13 and CNT concept; refreshed page count/date
- Analysis focus: microstructure-to-macroscopic performance chain (CPD functional groups, CNT dispersion, Cu₂O transition zone, dislocation/Orowan strengthening, conductivity and thermal stability) and research value of CNT for Cu-based electrocatalytic/catalytic hydrogenation.
[2026-06-08] ingest | Batch: CuO@PANI NO₃RR paper + Pd/Ni₅P₄ quinoline hydrogenation patent
- Source 1: Applied Catalysis B: Environmental 320, 121981 (2023) by Xu, Wen, Ren et al.; DOI 10.1016/j.apcatb.2022.121981
- Source 2: 中国专利 CN 118854361 A (2024) by 曹勇勇 (嘉兴大学)
- Raw sources captured: raw/papers/paper14-apcatb-2023-cuo-pani-nitrate-ammonia.md, raw/papers/paper15-patent-cn118854361-pd-ni5p4-quinoline-hydrogenation.md
- Entity pages created: entities/paper14-cuo-pani-nitrate-ammonia.md, entities/paper15-pd-ni5p4-quinoline-hydrogenation-patent.md
- Concept pages updated: concepts/copper-oxide-organic-electrosynthesis.md, concepts/cu2o-morphology-control.md
- Index updated: added Paper 14, Paper 15; refreshed page count to 21
- Note: Paper 14 SI not provided; patent has no SI equivalent